Color anodizing for implants – TioCol™

The “color coding” of implants and medical instruments made from titanium and titanium alloys is extremely useful to surgeons, both before and during surgery – it is much easier to distinguish between different types and sizes of osteosynthesis products, such as screws, wires, plates or intra-medullary nails when they are color coded. Medical products are color-coded in this way using the TioCol™ color anodizing process. Color-anodized titanium implants boast excellent biocompatibility regardless the color and the TioCol™ treatment also reduces the release of alloy elements from the titanium alloy. Implants and medical instruments with TioCol™ surfaces are ideal for laser marking – another very effective form of labelling products directly on the surface – before or after treatment.

Color anodizing TioCol™ – areas of application

  • Biocompatible surfaces due to passivating oxide layer
  • Reduced content of critical alloy elements in the oxide layer
  • No change in component dimensions
  • Application for color coding of implants and medical instruments
  • Laser marking possible before or after color anodizing

Color anodizing for TioCol™ processing of implants and medical instruments

KKS offers individual developed systems that are manufactured in-house.

We are proven outsourcing experts in color anodizing TioCol™ of implants.

Color anodizing for TioCol™ processing of implants and medical instruments

KKS offers individual developed systems that are manufactured in-house.

We are proven outsourcing experts in color anodizing TioCol™ of implants.

Color anodizing titanium implants – How it works:

During the TioCol™ process, which is often used in the medical technology sector, colors appear caused by a titanium oxide layer, creating an optical interference effect: incident light is reflected on the surface of the oxide layer (actually colorless) and on the base layer. The overlap of the reflected light waves (interference) results in a colorful appearance of the surface.

Graphic explaining the optical interference effect that enables color coding by means of color anodizing implants in the medical technology sector.

Different layer thicknesses result in different colors during color anodizing

Under normal ambient conditions, titanium spontaneously forms a 5 nm titanium oxide layer on the surface, which protects the base material against corrosion. There are many ways to increase this layer thickness. With TioCol™, for example, we use an electrochemical approach to produce a titanium oxide layer that measures up to 300 nm on implants.

Interference image of titanium, which forms the basis of color anodizing in the medical technology sector.

Color anodizing using the TioCol™ method in a KKS color anodizing system in real time

TioCol™ color anodizing technology

Depending on the requirements, the implants are first pre-treated (mechanical pre-treatment, cleaning, pickling). The color-specific thickness of the titanium oxide layer is achieved electrochemically during the TioCol™ anodizing process by applying direct voltage.

For this, the implants are electrically connected across a rack and energized as an anode in an aqueous electrolyte. There is a linear relationship here between the electrical direct voltage applied and the thickness of the oxide layer as well as the resulting specific interference color.

Illustration of the color anodizing process using electroplating.
Anodizing process by means of electroplating
Image of the relationship between the voltage and the titanium colors during the color anodizing of implants.

Possible colors with TioCol™ color anodizing

KKS color codes for the color coding of medical instruments by means of color anodizing.

The colors in the above overview are not colorfast and may deviate.